Pyridinolysis of Dibutyl Chlorothiophosphate in Acetonitrile
نویسندگان
چکیده
منابع مشابه
Kinetics and Mechanism of Pyridinolysis of Aryl Dithiocyclopentanecarboxylates in Acetonitrile
Kinetic studies on the pyridinolysis of aryl dithiocyclopentanecarboxyaltes 2 were carried out at 60.0 C in acetonitrile. In the aminolysis of 2, the βX values were 0.5 0.8 with anilines, and there was no breakpoint. However, in the pyridinolysis of 2, biphasic Brönsted plots were obtained, with a change in slope from a large value (βX ≅ 0.7) to a small value (βX ≅ 0.4) at pKa = 5.2. This was a...
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In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetra-hedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (-) anions and three uncoordinated CH(3)CN solvent mol-ecules. The three anions are disordered over two sites through a rotation along one of the F-P-F axes. The relative occupancies of the two sites for the F atoms are 0.643...
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activity in liver homogenate from di-2-ethylhexyl phthalate (DEHP)-treated rats. Ohyama9) showed in vitro that PAEs inhibited mitochondrial respiration, with di-n-butyl phthalte (DBP) showing the strongest effect, and he concluded that PAEs were inhibitors of electron and energy transfer systems but not uncouplers. Takahashi10) also found inhibitory effects of PAEs on respiration in vitro and a...
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ژورنال
عنوان ژورنال: Bulletin of the Korean Chemical Society
سال: 2012
ISSN: 0253-2964
DOI: 10.5012/bkcs.2012.33.3.1085